氯化氰,又名氯甲氰,是一种化合物,化学式为CNCl,为无色液体或气体,微甜,有剧du ,可溶于水、乙醇、乙mi等多数有机溶剂,溶于水后为弱酸性。化学反应活性很高,能与很多化学物质发生反应。受热易分解,接触水、水蒸气时易发生反应,甚至会发生剧烈的反应,同时会释放出剧du和腐蚀性的烟雾。可与氢氧化钠反应生成氰酸钠,与硫化钠反应生成硫氰酸钠,与氨或胺类反应生成氨基氰,与醇类反应生成三聚氰酸酯。
浩瀚色谱采用气相色谱法测定工业废气中的氯化氰含量.采用GC790型气相色谱仪,HH-CNCL-III色谱柱,采用外标法定量.氯化氰浓度在0.1~10 mol/mol范围内与峰面积呈良好的线性关系,相关系数大于0.999,9次重复测定结果的相对标准偏差小于4%,样品加标回收率为95%~104%.结果表明该方法简单,快速,测试结果准确可靠,满足废气中氯化氰含量的测试.
名称:填充柱
固定相:专用
规格:3m*3mm
型号:HH-CNCL-III
应用:工业氯化氰纯度及杂质测定
Cyanide chloride, also known as chloromethyl cyanide, is a compound with the chemical formula CNCl. It is a colorless liquid or gas, slightly sweet, and highly soluble in most organic solvents such as water, ethanol, and ethyl alcohol. After dissolving in water, it becomes weakly acidic. The chemical reactivity is high and can react with many chemical substances. It is prone to decomposition when heated, and can react with water or steam, even causing violent reactions, while releasing strong and corrosive smoke. It can react with sodium hydroxide to produce sodium cyanate, with sodium sulfide to produce sodium thiocyanate, with ammonia or amines to produce cyanamide, and with alcohols to produce cyanurate.
Haohan Chromatography uses gas chromatography to determine the content of cyanide chloride in industrial waste gas. The GC790 gas chromatograph, HH-CNCL-III chromatographic column, and external standard method are used for quantification. The concentration of cyanide chloride shows a good linear relationship with peak area in the range of 0.1-10 mol/mol, with a correlation coefficient greater than 0.999. The relative standard deviation of 9 repeated measurements is less than 4%, and the sample recovery rate is 95%~104%. The results show that this method is simple, fast, accurate and reliable, and can meet the testing of cyanide chloride content in waste gas
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