在气相流化床聚丙烯工艺中,反应器内的丙烷由原料丙烯带入,随排放气进入回收系统后排出。丙烷在反应器内不参与化学反应,其作用是与丙烯一起维持反应器C3分压和冷凝量的稳定,与氮气组成反应器内惰性组分的动态平衡。操作经验表明,当丙烷浓度维持在正常范围内时,会有效增加反应热的移除能力,保证聚合反应催化剂活性的相对稳定,同时具有降低丙烯单耗和抑制静电的作用。但如果反应器内的丙烷浓度偏高,特别是在生产负荷较高时,就会给产品出料以及回收系统带来波动,影响反应器内丙烯分压的正常维持,降低反应器的产率和抗干扰能力,给生产长周期平稳运行带来隐患。如果反应器内丙烷浓度偏高时能及时发现并调整,就会有效控制丙烷浓度在正常范围内。
浩瀚色(山东)应用技术开发有限公司,研制TCD气相色谱仪测定丙烯中丙烷,柱效高,分离好,分析时间短,结果满意。
名称:丙烯专用填充柱
型号:HH-Propylene-III
规格:3m*3mm,80-100目
*高温度:115°C
编号:20240516006
应用:丙烯中丙烷的测定 气相色谱法
In the gas-phase fluidized bed polypropylene process, propane in the reactor is introduced from the raw material propylene and discharged into the recovery system along with the exhaust gas. Propane does not participate in chemical reactions in the reactor. Its function is to maintain the stability of C3 partial pressure and condensation capacity in the reactor together with propylene, and to form a dynamic equilibrium of inert components in the reactor with nitrogen. Operating experience has shown that when the concentration of propane is maintained within the normal range, it can effectively increase the ability to remove reaction heat, ensure the relative stability of polymerization catalyst activity, and have the effect of reducing propylene consumption and suppressing static electricity. But if the propane concentration in the reactor is too high, especially at high production loads, it will cause fluctuations in the product discharge and recovery system, affecting the normal maintenance of propylene partial pressure in the reactor, reducing the yield and anti-interference ability of the reactor, and posing hidden dangers to the long-term stable operation of production. If the propane concentration in the reactor is too high and can be detected and adjusted in a timely manner, it will effectively control the propane concentration within the normal range.
Haohan Color (Shandong) Application Technology Development Co., Ltd. has developed a TCD gas chromatograph for the determination of propane in propylene, which has high column efficiency, good separation, short analysis time, and satisfactory results.
Name: Propylene specific filling column
Model: HH Propylene III
Specification: 3m * 3mm, 80-100 mesh
*High temperature: 115 ° C
Number: 20240516006
Application: Determination of propane in propylene by gas chromatography
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